Poly(styrene)-co-2-vinylpyridine copolymer as a novel solid-phase adsorbent for determination of manganese and zinc in foods and vegetables by FAAS

Tuzen M., ELİK A., Hazer B., ŞİMŞEK S., ALTUNAY N.

Food Chemistry, cilt.333, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 333
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.foodchem.2020.127504
  • Dergi Adı: Food Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, CAB Abstracts, Chimica, Communication Abstracts, Compendex, EMBASE, Food Science & Technology Abstracts, MEDLINE, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Zinc, Manganese, Food, Vegetable, Amphiphilic copolymer, Solid-phase microextraction, ATOMIC-ABSORPTION-SPECTROMETRY, GRAPHENE OXIDE, CARBON NANOTUBES, WATER SAMPLES, EXTRACTION, COPPER, PRECONCENTRATION, MICROEXTRACTION, CADMIUM, POLYMER
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

© 2020 Elsevier LtdThe aim of this study is to extract zinc and manganese from foods and vegetables using an amphiphilic copolymer adsorbent, poly(styrene)-co-2-vinylpyridine which was synthesized via reversible addition fragmentation chain transfer (RAFT) polymerization from styrene and 2-vinyl pyridine in the presence of a trithiocarbonate and 2,2′-azo-bis isobutyro nitrile (AIBN) in toluene solution under argon at 80 °C. Fourier Transform Infrared (FTIR) and proton nuclear magnetic resonance (1H NMR) spectroscopy were used in the characterization of the obtained copolymer. Under the optimum conditions, several validation variables such as uncertainty measurement, selectivity, robustness, precisions, matrix effects and accuracy were investigated. Taking an adsorption time of 15 min, detection limits of 0.04 μg L −1 and 0.2 μg L −1 and 7.9 μg L−1 and enrichment factors of 145 and 110 were obtained for Mn(II) and Zn(II), respectively. The method was successfully applied to the analysis of Mn(II) and Zn(II) in foods and vegetables.