Energy Storage Performance of Nitrogen Doped Reduced Graphene Oxide/Co-Doped Polyaniline Nanocomposites

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Altinisik H., Getiren B., ÇIPLAK Z., SOYSAL F., YILDIZ N.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.33, sa.2, ss.353-367, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 2
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1007/s10904-022-02456-0
  • Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Sayfa Sayıları: ss.353-367
  • Anahtar Kelimeler: Polyaniline, Graphene, Supercapacitor, Nitrogen doping, Nanocomposite, FACILE SYNTHESIS, SUPERCAPACITOR ELECTRODES, COMPOSITE, NANOTUBE, PANI
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

The design and exploration of carbon-based electrode materials have become highly significant for developing supercapacitor technology, which has attracted considerable attention in energy storage systems. Here, nitrogen-doped reduced graphene oxide (N-rGO) - Polyaniline (PANI) nanocomposites were synthesized by a facile two-step method in which in situ polymerization of aniline monomer was performed on hydrothermally synthesized N-rGO nanosheets in DBSA and H2SO4 medium for co-doping of PANI chains. The effects of various acid concentrations (DBSA:H2SO4 0.5 - 0.25:1 n/n) and N-rGO:aniline ratios (N-rGO:aniline 1:4-10 m/m) used in the preparation of the electrode material on the capacitive properties were investigated. It is found that the co-doped N-rGO-PANI nanocomposites exhibit a high specific capacitance of 346.3 F g(- 1) at 1 A g(- 1), remarkable rate capacity (99.9%, 1-10 A g(- 1)) and excellent cycle stability at 5 A g(- 1) (81.3%, 5000 cycles) in a two-electrode system. As a result, constructing co-doped PANI chains and N-doped rGO provided a viable and simple way to improve the capacitive performances of supercapacitors.