Half-sandwich Ruthenium(II) arene complexes bearing the azo-azomethine ligands: Electrochemical, computational, antiproliferative and antioxidant properties

Inan, Ayse; Sunbul, Ali; Ikiz, Mesut; Tayhan, Secil; BİLGİN, SEMA; Elmastas, Mahfuz; SAYIN, KORAY; CEYHAN, GÖKHAN; KÖSE, MUHAMMET; İSPİR, ESİN

doi:10.1016/j.jorganchem.2018.06.014

Half-sandwich Ruthenium(II) arene complexes bearing the azo-azomethine ligands: Electrochemical, computational, antiproliferative and antioxidant properties

Atıf İçin Kopyala

Inan A., Sunbul A. B., Ikiz M., Tayhan S. E., BİLGİN S., Elmastas M., ...Daha Fazla

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.870, ss.76-89, 2018 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 870
Basım Tarihi: 2018
Doi Numarası: 10.1016/j.jorganchem.2018.06.014
Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.76-89
Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

Three novel azo-azomethine ligands have been synthesized in an accomplished one-pot synthesis protocol. The mononuclear Ru(II) complexes of these azo-azomethine dyes were prepared and characterized by the combination of elemental analyses, IR, UV-Visible spectroscopy and H-1-C-13 NMR spectra. Solid state structures of 3, 4 and 7 were determined by single crystal X-ray diffraction studies. The electrochemical and photoluminescence properties of the compounds were studied. The 1931 CIE (x, y) chromaticity coordinates of the ligands and their metal complexes were investigated and the x, y values of the compounds were found to be close to the National Television Standard Committee (NTSC) standard. Quantum chemical calculation of related ligands and complexes are performed at B3LYP/6-31G(d, p) and B3LYP/6-31G(d, p) (LANL2DZ) level in vacuum.