Hydroxy phenyl hydrazides and their role as corrosion impeding agent: A detail experimental and theoretical study


Singh A. K., Chugh B., Singh M., Thakur S., Pani B., Guo L., ...Daha Fazla

JOURNAL OF MOLECULAR LIQUIDS, cilt.330, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 330
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.molliq.2021.115605
  • Dergi Adı: JOURNAL OF MOLECULAR LIQUIDS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, INSPEC
  • Anahtar Kelimeler: Toxicity, Solubility, XPS, MD, EIS, Contact angle, MILD-STEEL CORROSION, HYDROCHLORIC-ACID SOLUTION, CARBON-STEEL, ASSISTED SYNTHESIS, MAXIMUM HARDNESS, LATTICE ENERGIES, INHIBITION, DERIVATIVES, ADSORPTION, EXTRACT
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

This study presents synthesis of environmentally benign corrosion inhibitors, hydroxy acetophenone derivative namely, N'-(1-(2-hydroxyphenyl) ethylidene) acetohydrazide (ATOH), N'-(1-(2-hydroxyphenyl) ethylidene) benzohydrazide (BZOH), 2-(1-(2-hydroxyphenyl) ethylidene) hydrazine-1-carbothioamide (TSCOH) and N'-(1-(2-hydroxyphenyl) ethylidene) hydrazinecarbothiohydrazide (TCBOH) and full investigation of their protecting ability against corrosion of MS in 1 M HCl medium. A variety of electrochemical experimental techniques viz., electrochemical impedance spectroscopy, and potentiodynamic polarization coupled with different microscopic techniques viz., scanning electron microscopy, atomic force microscopy, and x-ray photoelectron spectroscopy were run to evaluate the corrosion resistive behaviour of inhibitors. The surface feature of mild steel was further analysed by measuring contact angle in different electrolytic solutions. Furthermore, these wet-chemical experimental outcomes are well complemented from results analysed from ab initio DFT study and MD simulation. Furthermore, the MD simulation outcomes helped in visualization of interaction and thereby adsorption of inhibitors on Fe (110) surface. (C) 2021 Elsevier B.V. All rights reserved.