PEPPSI-type 2-methyl-2-propenyl-functionalized N-heterocyclic carbene-palladium complexes: Synthesis, structural characterization and catalytic activity on Suzuki-Miyaura reaction

ŞAHİN N.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1177, ss.193-198, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1177
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.molstruc.2018.09.064
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.193-198
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

N-Heterocyclic carbenes (NHCs) have been known to be efficient ligands for the Suzuki-Miyaura cross-coupling. In this work, four novel 2-methyl-2-propenyl substituted N-heterocyclic carbene ligands (1a-d) were synthesized and they were used to produce four novel air-stable PEPPSI-type palladium-NHC complexes (2a-d). All of the new compounds were fully characterized by elemental analysis, H-1, C-13 NMR and FT-IR spectroscopies. In addition, prepared complexes (2a-d) were investigated as catalysts in the Suzuki-Miyaura coupling reaction under very mild conditions using a mixture of i-PrOH/water as a solvent and a base at the room temperature. Under optimal reaction conditions, the expected biaryl products were obtained in moderate to high yields. (C) 2018 Elsevier B.V. All rights reserved.