Reaction-Based Sensing of Fluoride Ions Using Built-in Triggers for Intramolecular Charge Transfer and Photoinduced Electron Transfer

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Bozdemir O. A., Sozmen F., Buyukcakir O., Guliyev R., Cakmak Y., Akkaya E. U.

ORGANIC LETTERS, cilt.12, sa.7, ss.1400-1403, 2010 (SCI-Expanded)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 12 Sayı: 7
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1021/ol100172w
  • Dergi Adı: ORGANIC LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1400-1403
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • Sivas Cumhuriyet Üniversitesi Adresli: Hayır

Özet

Two Bodipy derivatives with silyl-protected phenolic functionalities signal fluoride concentrations both in solution and in a poly(methyl methacrylate) matrix. The exact location of the "nascent" phenolate group Is Important. If it is at the meso position, photoinduced electron transfer is triggered; however, if it is in full conjugation via a styryl moiety to the Bodipy core, strong Intramolecular charge transfer is triggered, resulting in a large red shift in the absorbance peak. In either case, a selective methodology for fluoride sensing is the invariable result.