Nitrogen-doped graphene quantum dots/co-doped PANI binary nanocomposites as high-performance supercapacitor electrode materials

Getiren B., Altınışık H., ÇIPLAK Z., SOYSAL F., YILDIZ N.

Synthetic Metals, cilt.298, 2023 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 298
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.synthmet.2023.117451
  • Dergi Adı: Synthetic Metals
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Civil Engineering Abstracts
  • Anahtar Kelimeler: Co-doped PANI, N-GQDs, Nanocomposite, Supercapacitor
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

In this paper, a suitable and high-performance electrode material for practical applications was developed using a simple two-step approach. Here, we report that nitrogen-doped graphene quantum dots with co-doped polyaniline (N-GQDs-PANI) were fabricated by in situ polymerization as supercapacitor electrodes and that the effect of the amount of N-GQDs in the electrode material on the electrochemical performance was investigated. The integration of N-GQDs into co-doped PANI structure prevented the agglomeration of PANI and enabled the fabrication of N-GQDs as thin film on the surface. This modification improved the charge transfer of the N-GQDs-PANI electrode compared to N-GQDs and pure PANI electrodes, allowing it to exhibit superior electrochemical performance. The N-GQDs-PANI electrode has a specific capacitance of 503 F/g at a current density of 5 A/g with a capacitance retention of about 91.9 % after 10000 charge/discharge cycles.