Processable GO-PANI Nanocomposite for Supercapacitor Applications

ÇIPLAK Z.

JOURNAL OF ELECTRONIC MATERIALS, cilt.51, ss.1077-1088, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 51
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1007/s11664-021-09368-8
  • Dergi Adı: JOURNAL OF ELECTRONIC MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, PASCAL, Applied Science & Technology Source, Chemical Abstracts Core, Chimica, Compendex, Computer & Applied Sciences, INSPEC
  • Sayfa Sayıları: ss.1077-1088
  • Anahtar Kelimeler: Graphene oxide, polyaniline, nanocomposite, supercapacitor, GRAPHENE OXIDE, ELECTRODE MATERIAL, ENERGY-STORAGE, ELECTROCHEMICAL PERFORMANCE, CONTROLLABLE GROWTH, POLYANILINE, COMPOSITE, CARBON, FABRICATION, NANOFIBERS
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

In this study, graphene oxide (GO)-polyaniline (PANI) binary nanocomposite was prepared with a facile, green, and one-step in situ polymerization approach using dodecyl benzene sulfonic acid as a dopant and stabilizing agent to achieve production of processable GO-PANI nanocomposite for supercapacitor applications. The synthesized nanocomposites were characterized with Fourier transform infrared spectroscopy, x-ray diffraction, ultraviolet-visible spectroscopy (UV-Vis), and scanning electron microscopy. The electrochemical properties of supercapacitor electrode materials were analyzed by cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy (EIS) utilizing a two-electrode configuration. The effects of the amount of aniline-to GO-nanosheet ratio, used for preparation of the nanocomposite, on electrochemical performance were investigated. The GO-PANI nanocomposite demonstrated promising electrochemical performance towards supercapacitor applications. At 1 A/g current density, the GO-PANI electrodes show a high specific capacitance value of 269.3 F/g. In addition, the GO-PANI nanocomposite exhibited 81.3% specific capacitance retention after 10,000 cycles.