Optimizing the recovery of copper from electroplating rinse bath solution by hollow fiber membrane

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Oskay K. O., Kul M.

WATER SCIENCE AND TECHNOLOGY, cilt.72, ss.52-62, 2015 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 72
  • Basım Tarihi: 2015
  • Doi Numarası: 10.2166/wst.2015.187
  • Dergi Adı: WATER SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.52-62
  • Anahtar Kelimeler: CCD, copper, hollow fiber membrane, NDSX, optimization, recovery, NONDISPERSIVE SOLVENT-EXTRACTION, AQUEOUS-SOLUTIONS, OPTIMIZATION, PERFORMANCE, TECHNOLOGY, SEPARATION, CU(II), METALS, CR(VI), RSM
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

This study aimed to recover and remove copper from industrial model wastewater solution by non-dispersive solvent extraction (NDSX). Two mathematical models were developed to simulate the performance of an integrated extraction-stripping process, based on the use of hollow fiber contactors using the response surface method. The models allow one to predict the time dependent efficiencies of the two phases involved in individual extraction or stripping processes. The optimal recovery efficiency parameters were determined as 227 g/L of H2SO4 concentration, 1.22 feed/strip ratio, 450 mL/min flow rate (115.9 cm/min. flow velocity) and 15 volume % LIX 84-I concentration in 270 min by central composite design (CCD). At these optimum conditions, the experimental value of recovery efficiency was 95.88%, which was in close agreement with the 97.75% efficiency value predicted by the model. At the end of the process, almost all the copper in the model waste water solution was removed and recovered as CuSO4 center dot 5H(2)O salt, which can be reused in the copper electroplating industry.