A Novel Selective Deep Eutectic Solvent Extraction Method for Versatile Determination of Copper in Sediment Samples by ICP-OES

BAĞDA E., ALTUNDAĞ H., TÜZEN M., SOYLAK M.

BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, cilt.99, sa.2, ss.264-269, 2017 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 99 Sayı: 2
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1007/s00128-017-2065-y
  • Dergi Adı: BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.264-269
  • Anahtar Kelimeler: Extraction, Deep eutectic solvent, Sediment, Inductively coupled plasma optical emission spectrometry, POLYCYCLIC AROMATIC-HYDROCARBONS, LIQUID-PHASE MICROEXTRACTION, AGRICULTURAL SOIL, TRACE-METALS, SPECTROMETRY, ULTRASOUND, FAAS
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

In the present study, a simple, mono step deep eutectic solvent (DES) extraction was developed for selective extraction of copper from sediment samples. The optimization of all experimental parameters, e.g. DES type, sample/DES ratio, contact time and temperature were performed with using BCR-280 R (lake sediment certified reference material). The limit of detection (LOD) and the limit of quantification (LOQ) were found as 1.2 and 3.97 A mu g L-1, respectively. The RSD of the procedure was 7.5%. The proposed extraction method was applied to river and lake sediments sampled from Serpincik, Celtek, KA +/- zA +/- lA +/- rmak (Fadl and Tecer region of the river), Sivas-Turkey.