Integrated Catalytic and Energy Storage Performance of Grass Waste Derived Ni-Based Catalyst

Karakaş D. E., Horoz S., Durap F., Orak C., Kaya M.

Arabian Journal for Science and Engineering, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1007/s13369-024-09564-8
  • Dergi Adı: Arabian Journal for Science and Engineering
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Communication Abstracts, Metadex, Pollution Abstracts, zbMATH, Civil Engineering Abstracts
  • Anahtar Kelimeler: Grass waste, Hydrogen generation, Methanolysis, Ni-based catalyst, Supercapacitor
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

This study focuses on the optimization and characterization of a grass waste-derived catalyst, GW-Ni-Cat, for hydrogen generation via NaBH4 methanolysis, as well as its application in supercapacitors. Optimization experiments were conducted to determine the optimal conditions for acid concentration, metal concentration, carbonization temperature, and carbonization time. The catalyst was characterized using various techniques including FTIR, XRD, SEM, TEM, BET, and ICP-OES. Performance experiments demonstrated the catalyst's efficiency in hydrogen generation, with key factors such as catalyst amount, NaBH4 concentration, and temperature influencing the reaction kinetics. Reusability tests showed the catalyst's stability over multiple cycles. Electrochemical characterization revealed the suitability of GW-Ni-Cat as an electrode material for supercapacitors, with high specific capacitance values. Comparison with other bio-based supercapacitors demonstrated the superior performance of GW-Ni-Cat. Overall, this study presents GW-Ni-Cat as a versatile and efficient material for both hydrogen generation and energy storage applications.