Fast responding and selective near-IR Bodipy dye for hydrogen sulfide sensing

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Ozdemir T., Sozmen F., Mamur S., Tekinay T., Akkaya E. U.

CHEMICAL COMMUNICATIONS, cilt.50, sa.41, ss.5455-5457, 2014 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 50 Sayı: 41
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1039/c4cc00762j
  • Dergi Adı: CHEMICAL COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.5455-5457
  • Sivas Cumhuriyet Üniversitesi Adresli: Hayır

Özet

A Bodipy based, highly selective probe for hydrogen sulfide has been designed, synthesized and demonstrated to detect H2S in living cells. In this design, the reduction of two arylazido groups change the charge transfer characteristics of the 3,5-distyryl substituents on the Bodipy core, producing a 20 nm bathochromic spectral shift in the absorption band, and quenching of the emission by 85% compared to the original intensity, through photoinduced electron transfer.