Palladium-catalysed Suzuki-Miyaura cross-coupling with imidazolylidene ligands substituted by crowded resorcinarenyl and calixarenyl units

Sahin N., Semeril D., Brenner E., Matt D., KAYA C., Toupet L.

TURKISH JOURNAL OF CHEMISTRY, cilt.39, sa.6, ss.1171-1179, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 39 Sayı: 6
  • Basım Tarihi: 2015
  • Doi Numarası: 10.3906/kim-1503-82
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.1171-1179
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

Two N-heterocyclic carbene (NHC) palladium complexes of formula [PdBr2 (NHC)(pyridine)] in which the carbenic ring is flanked by sterically crowded cavitand substituents were prepared from appropriate imidazolium salts bearing either two resorcinarene or a combination of resorcinarene and calixarene fragments. Both complexes displayed high stability and good activities in the cross-coupling of aryl bromides with phenyl boronic acid. One of the imidazolium salts was characterised by an X-ray diffraction study.