The adsorption properties of the corm tunic structure of Crocus (Iridaceae) and its use as a biomarker for the environmental concentration of uranium

Creative Commons License

Koçak N., Çoktaş F., ŞİMŞEK S.

Journal of Radioanalytical and Nuclear Chemistry, cilt.333, sa.5, ss.2439-2448, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 333 Sayı: 5
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1007/s10967-024-09475-w
  • Dergi Adı: Journal of Radioanalytical and Nuclear Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Analytical Abstracts, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Food Science & Technology Abstracts, INSPEC, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.2439-2448
  • Anahtar Kelimeler: Adsorption, Corm tunic, Crocus, Uranyl
  • Sivas Cumhuriyet Üniversitesi Adresli: Evet

Özet

In this study, we investigated whether the corm tunic structure, which is the underground part of the Crocus (Iridaceae) plant, can be used for adsorption and recovery/removal of uranium from an aqueous solution. The characterization of this structure, which has not been studied for its interaction with metals before, has been elucidated by point zero charge (PZC), FTIR, and SEM analyses. Extensive investigations were conducted on the adsorption properties of the biomass used and the pH, temperature, time, adsorbent dosage, and uranyl ion concentration variables were optimized. The experimental data were interpreted using theoretical adsorption models. The Langmuir model revealed a maximum adsorption capacity of the material to be 0.286 mol kg−1. Adsorption kinetics were also described using pseudo-first order, pseudo-second order, Elovich, and intra-particular diffusion models. It is shown that the adsorption pH reaches the highest adsorption at the natural pH of the uranium solution. Experimental studies showed that the adsorption was endothermic and spontaneous. It has been shown that this biomaterial can be used as an adsorbent for the removal of uranium as well as a biomarker for determining the environmental uranium concentration.